Let`s talk about compounds: 610-09-3

Compound(610-09-3)Formula: C8H12O4 received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(cis-Cyclohexane-1,2-dicarboxylic acid), if you are interested, you can check out my other related articles.

Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 610-09-3, is researched, SMILESS is O=C([C@H]1[C@@H](C(O)=O)CCCC1)O, Molecular C8H12O4Journal, Article, Acta Crystallographica, Section E: Structure Reports Online called catena-Poly[[dimethyltin(IV)]-μ-cis-cyclohexane-1,2-dicarboxylato], Author is Wang, Yuerong; Zhang, Rufen; Li, Yongxin, the main research direction is tin cyclohexanedicarboxylato bridged dimethyl polymeric complex crystal structure; supramol mol structure tin cyclohexanedicarboxylato bridged dimethyl polymeric complex.Formula: C8H12O4.

The title complex, [Sn(CH3)2(C8H10O4)]n, was synthesized from cis-cyclohexane-1,2-dicarboxylic acid and dimethyltin dichloride. The complex has a bridging bis-bidentate carboxylate group resulting in a zig-zag chain structure parallel to [001]. The Sn atom is six-coordinated and displays a distorted octahedral geometry. Crystallog. data are given.

Compound(610-09-3)Formula: C8H12O4 received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(cis-Cyclohexane-1,2-dicarboxylic acid), if you are interested, you can check out my other related articles.

Reference:
Benzisoxazole – Wikipedia,
Benzisoxazole – an overview | ScienceDirect Topics

Top Picks: new discover of 610-09-3

Compound(610-09-3)COA of Formula: C8H12O4 received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(cis-Cyclohexane-1,2-dicarboxylic acid), if you are interested, you can check out my other related articles.

COA of Formula: C8H12O4. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: cis-Cyclohexane-1,2-dicarboxylic acid, is researched, Molecular C8H12O4, CAS is 610-09-3, about Novel CdII coordination polymers (1-D, 2-D to 3-D) constructed from 1,2-cyclohexanedicarboxylate and various bipyridyl ligands. Author is Kim, Eun Young; Park, Hyun Min; Kim, Ha-Yeong; Kim, Jin Hoon; Hyun, Min Young; Lee, Ju Hoon; Kim, Cheal; Kim, Sung-Jin; Kim, Youngmee.

Four CdII-(e,a-cis-1,2-chdc) complexes, [Cd(H2O)(1,2-chdc)(2,2′-bpy)] 1, [Cd(1,2-chdc)(bpe)]n 2, [Cd2(1,2-chdc)(4,4′-bpy)2]n 3A, and [Cd(H2O)(1,2-chdc)(4,4′-bpy)2]n·3n(H2O) 3B (1,2-chdc = cis-1,2-cyclohexanedicarboxylate), with different assistant ligands (2,2′-bipyridine (2,2′-bpy), 1,2-bis(4-pyridyl)ethene (bpe), and 4,4′-bipyridine (4,4′-bpy)) were synthesized and their structures were determined Depending on the assistant ligands, the structures and dimensionalities of CdII-(e,a-cis-1,2-chdc) complexes were varied. Two carboxylates in e,a-cis-1,2-chdc coordinate to CdII ions in chelating (η1:η1), bridging (η1:η1:μ2), and chelating/bridging (η2:η1:μ2) modes. Photoluminescence study of the compounds 1 and 2 showed emission of compound 1 was observed at 348 nm, while relatively weak luminescence was displayed at 516 nm for 2. The thermal stabilities of these complexes were also examined

Compound(610-09-3)COA of Formula: C8H12O4 received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(cis-Cyclohexane-1,2-dicarboxylic acid), if you are interested, you can check out my other related articles.

Reference:
Benzisoxazole – Wikipedia,
Benzisoxazole – an overview | ScienceDirect Topics

Extracurricular laboratory: Synthetic route of 610-09-3

Compound(610-09-3)Electric Literature of C8H12O4 received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(cis-Cyclohexane-1,2-dicarboxylic acid), if you are interested, you can check out my other related articles.

The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: cis-Cyclohexane-1,2-dicarboxylic acid(SMILESS: O=C([C@H]1[C@@H](C(O)=O)CCCC1)O,cas:610-09-3) is researched.SDS of cas: 14694-95-2. The article 《Poly[(μ6-rac-cis-cyclohexane-1,2-dicarboxylato)strontium]》 in relation to this compound, is published in Acta Crystallographica, Section C: Crystal Structure Communications. Let’s take a look at the latest research on this compound (cas:610-09-3).

In the title layered coordination polymer, [Sr(C8H10O4)]n, the strontium ion adopts a distorted square-antiprismatic SrO8 geometry, arising from its coordination by six different cis-cyclohexane-1,2-dicarboxylate dianions (two bidentate and four monodentate). Within the dianion, the cyclohexane ring adopts a chair conformation and the dihedral angle between the planes of the -CO2- groups is 80.4 (6)°. The polyhedral linkage pattern leads to (100) sheets in the crystal in which the SrO8 groups share triangular faces and edges in which the Sr···Sr topol. connectivity is a 63 net. The crystal studied was a nonmerohedral twin, with the components related by a 180° rotation about [100].

Compound(610-09-3)Electric Literature of C8H12O4 received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(cis-Cyclohexane-1,2-dicarboxylic acid), if you are interested, you can check out my other related articles.

Reference:
Benzisoxazole – Wikipedia,
Benzisoxazole – an overview | ScienceDirect Topics

Simple exploration of 37443-42-8

Compound(37443-42-8)COA of Formula: C6H10O3 received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(Methyl tetrahydrofuran-2-carboxylate), if you are interested, you can check out my other related articles.

COA of Formula: C6H10O3. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: Methyl tetrahydrofuran-2-carboxylate, is researched, Molecular C6H10O3, CAS is 37443-42-8, about Synthesis of mono-acylation piperazine compounds. Author is Wang, Hong-fei; Zuo, Zheng-long; Yang, Qing-lai; Shen, Xu-ji; Zhao, Xin-feng; Zheng, Xiao-hui.

1-(2-Furoyl)piperazine (90.6%) and 1-(terahydro-2-furoyl)piperazine were synthesized by the esterification of 2-furoic acid and 2-tetrahydrofuroic acid with methanol, and then amidation with piperazine, resp. The structures were characterized by 1H NMR and IR.

Compound(37443-42-8)COA of Formula: C6H10O3 received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(Methyl tetrahydrofuran-2-carboxylate), if you are interested, you can check out my other related articles.

Reference:
Benzisoxazole – Wikipedia,
Benzisoxazole – an overview | ScienceDirect Topics

Extracurricular laboratory: Synthetic route of 37443-42-8

Compound(37443-42-8)Safety of Methyl tetrahydrofuran-2-carboxylate received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(Methyl tetrahydrofuran-2-carboxylate), if you are interested, you can check out my other related articles.

Safety of Methyl tetrahydrofuran-2-carboxylate. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: Methyl tetrahydrofuran-2-carboxylate, is researched, Molecular C6H10O3, CAS is 37443-42-8, about Palladium-catalyzed asymmetric hydrogenation of furan carboxylic acids. Author is Maris, Mihaela; Huck, Wolf-Rudiger; Mallat, Tamas; Baiker, Alfons.

Enantioselective hydrogenation of aromatic and heteroaromatic compounds is the field where chirally modified metal hydrogenation catalysts have the biggest potential compared to homogeneous chiral transition metal complexes. Here we report the hydrogenation of furan and benzofuran carboxylic acids over a cinchonidine-modified 5 wt% Pd/Al2O3 catalyst. (S)-Tetrahydrofuran-2-carboxylic acid was synthesized in 4 h at rt and 30 bar with 95% yield and 32% ee. The ee was lower in the hydrogenation of methylfuran carboxylic acids but up to 100% de was achieved. In the slow hydrogenation of benzofuran-2-carboxylic acid, the ee went up to 50% at 29% yield. The potential application of the method is limited by the competing hydrogenation of the quinoline rings of cinchonidine in the latter reaction, necessitating the feeding of small amounts of cinchonidine during reaction. Still, this simple method using an easily available chiral modifier and catalyst affords the highest rate and ee reported so far in the catalytic asym. hydrogenation of furan and benzofuran carboxylic acids, and it may be an attractive route in combination with optical resolution We assume that the reaction mechanism is analogous to that described for α,β-unsaturated carboxylic acids over the same catalyst, involving a 1:2-type interaction between the cinchonidine and the acid dimer.

Compound(37443-42-8)Safety of Methyl tetrahydrofuran-2-carboxylate received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(Methyl tetrahydrofuran-2-carboxylate), if you are interested, you can check out my other related articles.

Reference:
Benzisoxazole – Wikipedia,
Benzisoxazole – an overview | ScienceDirect Topics

Extended knowledge of 3326-71-4

Compound(3326-71-4)Recommanded Product: 3326-71-4 received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(2-Furoic hydrazide), if you are interested, you can check out my other related articles.

Wu, Yuan-Yuan; Shao, Wu-Bin; Zhu, Jian-Jun; Long, Zhou-Qing; Liu, Li-Wei; Wang, Pei-Yi; Li, Zhong; Yang, Song published the article 《Novel 1,3,4-Oxadiazole-2-carbohydrazides as Prospective Agricultural Antifungal Agents Potentially Targeting Succinate Dehydrogenase》. Keywords: oxadiazolecarbohydrazide agricultural antifungal targeting succinate dehydrogenase; 1,3,4-oxadiazole; bioactivity; carbohydrazide; succinate dehydrogenase inhibitor.They researched the compound: 2-Furoic hydrazide( cas:3326-71-4 ).Recommanded Product: 3326-71-4. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:3326-71-4) here.

A novel simple 1,3,4-oxadiazole-2-carbohydrazides was reported to discover low-cost and versatile antifungal agents. Bioassay results suggested that a majority of the designed compounds were extremely bioactive against four types of fungi and two kinds of oomycetes. This extreme bioactivity was highlighted by the applausive inhibitory effects of compounds 4b, 4h, 5c, 5g, 5h, 5i, 5m, 5p, 5t, and 5v against Gibberella zeae, affording EC50 values ranging from 0.486μg/mL to 0.799μg/mL, which were superior to that of fluopyram (2.96μg/mL) and comparable to those of carbendazim (0.947μg/mL) and prochloraz (0.570μg/mL). Meanwhile, compounds 4g, 5f, 5i, and 5t showed significant actions against Fusarium oxysporum with EC50 values of 0.652, 0.706, 0.813, and 0.925μg/mL, resp. Pharmacophore exploration suggested that the N’-phenyl-1,3,4-oxadiazole-2-carbohydrazide pattern is necessary for the bioactivity. Mol. docking of 5h with succinate dehydrogenase (SDH) indicated that it can completely locate the inside of the binding pocket via hydrogen-bonding and hydrophobic interactions, revealing that this novel framework might target SDH. This result was further verified by the significant inhibitory effect on SDH activity. In addition, SEM patterns were performed to elucidate the anti-G. zeae mechanism. Given these features, this type of frameworks is a suitable template for future exploration of alternative SDH inhibitors against plant microbial infections.

Compound(3326-71-4)Recommanded Product: 3326-71-4 received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(2-Furoic hydrazide), if you are interested, you can check out my other related articles.

Reference:
Benzisoxazole – Wikipedia,
Benzisoxazole – an overview | ScienceDirect Topics

The effect of the change of synthetic route on the product 37443-42-8

Compound(37443-42-8)Application In Synthesis of Methyl tetrahydrofuran-2-carboxylate received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(Methyl tetrahydrofuran-2-carboxylate), if you are interested, you can check out my other related articles.

Application In Synthesis of Methyl tetrahydrofuran-2-carboxylate. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: Methyl tetrahydrofuran-2-carboxylate, is researched, Molecular C6H10O3, CAS is 37443-42-8, about Cannizzaro reaction of aldehydes in TMAH thermochemolysis.

Recently, tetramethylammonium hydroxide (TMAH) was advantageously used in the anal. pyrolysis of polymers, but yielded a great amount of carboxylic acid Me esters which were absent in conventional pyrolysis. The experiments with model compounds such as furaldehyde, benzaldehyde, hydroxy-, methoxy-, dimethoxybenzaldehyde and vanillin show that TMAH can react not only as a methylating and/or hydrolyzing agent but also with aldehydes according to a Cannizzaro reaction and the reaction products can be in-situ methylated to the corresponding esters and ethers.

Compound(37443-42-8)Application In Synthesis of Methyl tetrahydrofuran-2-carboxylate received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(Methyl tetrahydrofuran-2-carboxylate), if you are interested, you can check out my other related articles.

Reference:
Benzisoxazole – Wikipedia,
Benzisoxazole – an overview | ScienceDirect Topics

A small discovery about 3326-71-4

Compound(3326-71-4)Name: 2-Furoic hydrazide received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(2-Furoic hydrazide), if you are interested, you can check out my other related articles.

Name: 2-Furoic hydrazide. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: 2-Furoic hydrazide, is researched, Molecular C5H6N2O2, CAS is 3326-71-4, about BOPAHY: a doubly chelated highly fluorescent pyrrole-acyl hydrazone -BF2 chromophore. Author is Pookkandam Parambil, Shandev; de Jong, Flip; Veys, Koen; Huang, Jianjun; Veettil, Santhini Pulikkal; Verhaeghe, Davy; Van Meervelt, Luc; Escudero, Daniel; Van der Auweraer, Mark; Dehaen, Wim.

New easily functionalisable and highly fluorescent BOPAHY chromophores were synthesized via a 1-pot two-step reaction starting from com. available pyrrole-2-carbaldehydes and resp. acyl hydrazides in the presence of BF3·OEt2. Most importantly, all BOPAHY dyes show excellent photophys. properties with quantum yields up to 0.92. Steady-state spectroscopy and quantum chem. calculations provide a first insight into these promising properties.

Compound(3326-71-4)Name: 2-Furoic hydrazide received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(2-Furoic hydrazide), if you are interested, you can check out my other related articles.

Reference:
Benzisoxazole – Wikipedia,
Benzisoxazole – an overview | ScienceDirect Topics

Top Picks: new discover of 610-09-3

Compound(610-09-3)Category: benzisoxazole received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(cis-Cyclohexane-1,2-dicarboxylic acid), if you are interested, you can check out my other related articles.

In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Application of the cyano ester ring closure to five- and six-membered rings, published in 1938, which mentions a compound: 610-09-3, mainly applied to , Category: benzisoxazole.

cf. F. and Kao, C. A. 23, 2424. Et α,α’-dibromopimelate and KCN in absolute EtOH, refluxed for 60 hrs., give 80-8% of Et 1-cyano-1,2-cyclopentanedicarboxylate, b2 126-8°, d420 1.108, nD20 1.4560; hydrolysis with concentrated HCl gives a mixture of trans- and cis-1,2-cyclopentanedicarboxylic acid (Perkins, J. Chem. Soc. 65, 572(1894)). Similarly Et α,α’-dibromosuberate yields 48-55% of Et 1-cyano-1,2-cyclohexanedicarboxylate, b2 129-30°, d420 1.082, nD20 1.4570; hydrolysis with 20% HCl yields a mixture of the 2 1,2-cyclohexanedicarboxylic acids, the trans-isomer being obtained pure (Baeyer, Ann. 258, 213(1890)). Et α,α’-dibromoazelate and Et α,α’-dibromosebacate failed to give detectable quantities of the cyclic CN esters containing 7- or 8-membered rings.

Compound(610-09-3)Category: benzisoxazole received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(cis-Cyclohexane-1,2-dicarboxylic acid), if you are interested, you can check out my other related articles.

Reference:
Benzisoxazole – Wikipedia,
Benzisoxazole – an overview | ScienceDirect Topics

Derivation of elementary reaction about 610-09-3

Compound(610-09-3)Product Details of 610-09-3 received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(cis-Cyclohexane-1,2-dicarboxylic acid), if you are interested, you can check out my other related articles.

The reaction of an aromatic heterocycle with a proton is called a protonation. One of articles about this theory is 《Improved synthesis of cis-Δ4-tetrahydrophthalic anhydride and cis-hexahydrophthalic acid》. Authors are Jenkins, Edward F.; Costello, Edward J..The article about the compound:cis-Cyclohexane-1,2-dicarboxylic acidcas:610-09-3,SMILESS:O=C([C@H]1[C@@H](C(O)=O)CCCC1)O).Product Details of 610-09-3. Through the article, more information about this compound (cas:610-09-3) is conveyed.

Maleic anhydride (1 mole) in 150 ml. C6H6, cooled to 5°, 54 g. liquid (CH2:CH)2 added, and the mixture heated to 115° (within 15 min. the temperature rises to 145° and the pressure to 11 atm.) and allowed to stand overnight, gives 90% cis-Δ4-tetrahydrophthalic anhydride (I), m. 103-4°. I (30.4 g.) in 150 ml. AcOH, hydrogenated 0.5 hr. over 200 mg. Pt oxide at room temperature and 4.5 atm., and the mixture boiled with H2O, gives 90% cis-hexahydrophthalic acid, m. 190-1°.

Compound(610-09-3)Product Details of 610-09-3 received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(cis-Cyclohexane-1,2-dicarboxylic acid), if you are interested, you can check out my other related articles.

Reference:
Benzisoxazole – Wikipedia,
Benzisoxazole – an overview | ScienceDirect Topics