In chemical reaction engineering, simulations are useful for investigating and optimizing a particular reaction process or system., Application In Synthesis of Lithium acetate dihydrate, Introducing a new discovery about 6108-17-4, Name is Lithium acetate dihydrate, molecular formula is C2H7LiO4, belongs to benzisoxazole compound. In a document, author is Berton, Mateo.
Reactivity of Lithium beta-Ketocarboxylates: The Role of Lithium Salts
Lithium beta-ketocarboxylates 1(COOLi), prepared by the reaction of lithium enolates 2(Li+) with carbon dioxide, readily undergo decarboxylative disproportionation in THF solution unless in the presence of lithium salts, in which case they are indefinitely stable at room temperature in inert atmosphere. The availability of stable THF solutions of lithium beta-ketocarboxylates 1(COOLi) in the absence of carbon dioxide allowed reactions to take place with nitrogen bases and alkyl halides 3 to give alpha-alkyl ketones 1(R) after acidic hydrolysis. The sequence thus represents the use of carbon dioxide as a removable directing group for the selective monoalkylation of lithium enolates 2(Li+). The roles of lithium salts in preventing the disproportionation of lithium beta-ketocarboxylates 1(COOLi) and in determining the course of the reaction with bases and alkyl halides 3 are discussed.
Application In Synthesis of Lithium acetate dihydrate, Because enzymes can increase reaction rates by enormous factors and tend to be very specific, typically producing only a single product in quantitative yield, they are the focus of active research.you can also check out more blogs about 6108-17-4.
Reference:
Benzisoxazole – Wikipedia,
,Benzisoxazole – an overview | ScienceDirect Topics