Chemical Research Letters, May 2021. In classical electrochemical theory, both the electron transfer rate and the adsorption of reactants at the electrode control the electrochemical reaction. In an article, author is Jadhav, Prakash D., once mentioned the application of 505-48-6, Name is Octanedioic acid, molecular formula is C8H14O4, molecular weight is 174.1944, MDL number is MFCD00004428, category is benzisoxazole. Now introduce a scientific discovery about this category, Formula: https://www.ambeed.com/products/505-48-6.html.
This work describes two distinct annulations between ynamides and 1,2-benzisoxazoles with chemo-selectivity controlled by ligands. With IPrAuCl/AgNTf2, aryl-substituted ynamides undergo [5+2]-annulation reactions, whereas P(t-Bu)(2)(o-biphenyl)AuCl/AgNTf2 alters the chemoselectivity of the same ynamides to implement [5+1]-annulation reactions. C-13-Labeling experiments confirm that a 1,2-sulfonamide shift is involved in the [5+1]-annulation process. A plausible mechanism is postulated to rationalize the mechanisms of the two annulations.
But sometimes, even after several years of basic chemistry education, it is not easy to form a clear picture on how they govern reactivity! 505-48-6, you can contact me at any time and look forward to more communication. Formula: https://www.ambeed.com/products/505-48-6.html.
Reference:
Benzisoxazole – Wikipedia,
,Benzisoxazole – an overview | ScienceDirect Topics