Chemical Research Letters, May 2021. In classical electrochemical theory, both the electron transfer rate and the adsorption of reactants at the electrode control the electrochemical reaction. In an article, author is FERRIS, DC, once mentioned the application of 1113-38-8, Name is Ammonium oxalate, molecular formula is C2H8N2O4, molecular weight is 124.1, MDL number is MFCD00013308, category is benzisoxazole. Now introduce a scientific discovery about this category, Application of 1113-38-8.
RATE OF DECARBOXYLATION OF BENZISOXAZOLE-3-CARBOXYLATE IONS AS A PROBE OF SOLVATION IN BIOLOGICAL AND OTHER MEDIA
The influence of solvent donor-acceptor properties and polarity on the rates of decarboxylation of benzisoxazole-3-carboxylate ions is analyzed with the unified solvation model. When the dissolved species is a separated ion pair, solvent polarity decreases the rate. When an equilibrium exists between an ion pair and the dissociated ion pair, solvent polarity and donor strength increase the rate by increasing the extent of dissociation. Hydrogen bonding to the carboxylate functionality causes a significant decrease in rate. When using this probe to measure the solvation properties of solvents, micelles, polymers, or biological assemblies, these different effects must be sorted out to interpret the influence of the medium on the observed rate. The unified solvation model provides a means of sorting out these various contributions.
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Reference:
Benzisoxazole – Wikipedia,
,Benzisoxazole – an overview | ScienceDirect Topics