The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: cis-Cyclohexane-1,2-dicarboxylic acid(SMILESS: O=C([C@H]1[C@@H](C(O)=O)CCCC1)O,cas:610-09-3) is researched.HPLC of Formula: 652148-90-8. The article 《Photoreduction of carbon dioxide to its radical anion by nickel cluster [Ni3(μ3-I)2(dppm)3]: formation of two carbon-carbon bonds via addition of carbon dioxide radical anion to cyclohexene》 in relation to this compound, is published in Journal of the American Chemical Society. Let’s take a look at the latest research on this compound (cas:610-09-3).
The trinuclear cluster Ni3(μ3-I)2(dppm)3, (1) [dppm = bis(diphenylphosphino)methane] is formed by conproportionation of Ni(COD)2 and NiI2 in the presence of dppm. Cluster 1 and its singly oxidized radical cation (2) have been characterized spectroscopically and by x-ray diffraction. Cluster 2 exhibits a slight Jahn-Teller distortion of its triangular nickel framework. Irradiation of 1 in the presence of CO2 results in photochem. electron transfer to produce CO2•- and 2. The CO2•- can be trapped by H-atom abstraction from toluene to produce formate ion or with cyclohexene to form cis- and trans-1,2-cyclohexanedicarboxylic acid. The radical anion disproportionation products, carbonate and CO, are observed in the absence of a trapping reagent for CO2•-.
In some applications, this compound(610-09-3)COA of Formula: C8H12O4 is unique.If you want to know more details about this compound, you can contact with the author or consult more relevant literature.
Reference:
Benzisoxazole – Wikipedia,
Benzisoxazole – an overview | ScienceDirect Topics