The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: cis-Cyclohexane-1,2-dicarboxylic acid( cas:610-09-3 ) is researched.Product Details of 610-09-3.Huang, Fu-Ping; Lei, Jing-Bin; Yu, Qing; Bian, He-Dong; Yan, Shi-Ping published the article 《The structural diversity and luminescent properties of Zn(II) coordination assemblies with cyclohexane (or cyclohexene) dicarboxylate anions and two positional isomeric ligands》 about this compound( cas:610-09-3 ) in Polyhedron. Keywords: preparation zinc cyclohexene cyclohexane carboxylate bispyridyltriazole coordination polymer; crystal structure zinc cyclohexene cyclohexane carboxylate bispyridyltriazole coordination polymer; luminescence zinc cyclohexene cyclohexane carboxylate bispyridyltriazole coordination polymer. Let’s learn more about this compound (cas:610-09-3).
Four Zn(II) coordination polymers, {[Zn(chedc)(4,4′-Hbpt)]}n (1), {[Zn3(chadc)2(4,4′-Hbpt)2(4,4′-bpt)2]·3H2O}n (2), {[Zn2(chadc)2(3,3′-Hbpt)]}n (3) and {[Zn2(chedc)2(3,3′-Hbpt)]·H2O}n (4) (chadc = cis-1,2-cyclohexanedicarboxylate anion, chedc = cis-4-cyclohexene-1,2-dicarboxylate anion, 4,4′-Hbpt = 1H-3,5-bis(4-pyridyl)-1,2,4-triazole, 3,3′-Hbpt = 1H-3,5-bis(3-pyridyl)-1,2,4-triazole) were produced by the reaction of two positional isomeric dipyridyl bridging ligands and two dicarboxylate anions with Zn(II) salts under hydrothermal conditions. Structural anal. reveals that 1 exhibits a double-chain and 2 exhibits a 3-dimensional network with a (62.10)2(64.102) topol., while 3 and 4 show similar layer structures. The luminescent properties of these complexes were briefly studied.
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Reference:
Benzisoxazole – Wikipedia,
Benzisoxazole – an overview | ScienceDirect Topics