In an article, author is Chimichi, Stefano, once mentioned the application of 532-32-1, Name: Sodium benzoate, Name is Sodium benzoate, molecular formula is C7H5NaO2, molecular weight is 144.1032, MDL number is MFCD00012463, category is Benzisoxazole. Now introduce a scientific discovery about this category.
First example of diels-alder reaction of 4-(1-ethenylsubstituted)-3-methylisoxazoles with acetylenedicarboxylates
The first example of a [4+2] cycloaddition reaction of 4-(1-ethenylsubstituted)isoxazoles with acetylenedicarboxylates is reported, while the corresponding 5-substituted isomers do not react with the same dienophile; density functional theory (DFT) calculation indicate the electronic origin of the different behaviour.
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Reference:
Benzisoxazole – Wikipedia,
,Benzisoxazole – an overview | ScienceDirect Topics