Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 610-09-3, is researched, Molecular C8H12O4, about Reduction mechanism of cyclohexene-1,2-dicarboxylic acid, the main research direction is electrochem reduction kinetics cyclohexenedicarboxylic acid; mechanism electrochem reduction cyclohexenedicarboxylic acid; stereochem electrochem reduction cyclohexenedicarboxylic acid; cyclohexanedicarboxylic acid.SDS of cas: 610-09-3.
Reduction mechanism of cyclohexene-1,2-dicarboxylic acid (I) was polarog. examined at pH 0-6. The first of the 3 waves that appeared was due to the adsorption of the product in strongly acid media. The 2nd wave was interpreted as due to a CEC (chem.-electrode-chem.) process involving preprotonation of the acid. The 3rd wave that appeared only in weakly acid media involved a CEC mechanism by which the free acid was reduced. The rate constant of the protonation of the monoanion from I was calculated Controlled-potential electrolysis produced a mixture of trans- and cis-cyclohexanedicarboxylic acid in high yield at pH 0-6. The stereoisomeric ratio of the products was influenced by pH; this was due to the difference of the stability of the reaction intermediates.
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Reference:
Benzisoxazole – Wikipedia,
Benzisoxazole – an overview | ScienceDirect Topics