Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 3326-71-4, is researched, SMILESS is O=C(C1=CC=CO1)NN, Molecular C5H6N2O2Journal, Wuji Huaxue Xuebao called Synthesis, crystal structures, and characterization of three zinc complexs with different acylhydrazone-type schiff base ligands, Author is Xie, Qing-fan; Chen, Yan-min, the main research direction is crystal structure zinc complex acylhydrazone type schiff base ligand.COA of Formula: C5H6N2O2.
Three zinc complexes, namely [Zn(Lss)(phen)(DMF)] (1), {[Zn (HLdis)]2·2CH3OH}n (2) and [Zn(Baf)2]·CH3OH (3), formed from different acylhydrazone-type Schiff base ligands were synthesized by using different methods, and the compounds were characterized by IR, UV-Vis spectra and TGA. The X-ray diffraction analyses revealed that 1 and 3 crystallized in the triclinic space group P1̅ while 2 in monoclinic system space group P21/n. In 1 and 3, coordination number of the Zn (II) was six, and the centric atom located in a distorted octahedron geometry, while in 2 Zn (II) was five-coordination in a distorted square-pyramidal geometry. The precursor of 3 was pyrazoline derivative with the formula C15H14N2O3 (Pzl) crystallizing in monoclinic system space group P21/c. Due to the coordination of Zn (II) causing the intramol. rearrangement of Pzl, the ring open product HBaf in the form of an acylhydrazone structure coordinated with Zn (II) to form complex 3.
If you want to learn more about this compound(2-Furoic hydrazide)COA of Formula: C5H6N2O2, you may wish to communicate with the author of the article,or consult the relevant literature related to this compound(3326-71-4).
Reference:
Benzisoxazole – Wikipedia,
Benzisoxazole – an overview | ScienceDirect Topics