Ling, Fei; Liu, Tao; Xu, Chao; He, Jiaying; Zhang, Wangqin; Ling, Changwu; Liu, Lei; Zhong, Weihui published the artcile< Divergent electrolysis for the controllable coupling of thiols with 1,2-dichloroethane: a mild approach to sulfide and sulfoxide>, Related Products of 84163-77-9, the main research area is chloroethyl sulfide green preparation; thiol dichloroethane electrochem sulfidation; sulfoxide chloroethyl green preparation; dichloroethane thiol electrochem sulfoxidation.
A safe, practical and eco-friendly electrochem. methodol. was reported for the controllable dechloro-coupling of 1,2-dichloroethane (DCE) with thiols, providing value-added β-chloroethyl-sulfides ArSCH2CH2Cl [Ar = Ph, 4-MeC6H4, 2-naphthyl, etc.] and β-chloroethyl-sulfoxides Ar1S(O)CH2CH2Cl [Ar1 = Ph, 2-BrC6H4, 2,4-di-MeC6H3, etc.], which served as versatile building blocks in the efficient late-stage conversion to bioactive mols. The mildness and practicality of this protocol was further demonstrated by the total synthesis of anti-gout drug sulfinpyrazone in a 32% total yield over three steps.
Green Chemistry published new progress about Electrochemical reaction. 84163-77-9 belongs to class benzisoxazole, and the molecular formula is C12H13FN2O, Related Products of 84163-77-9.
Referemce:
Benzisoxazole – Wikipedia,
Benzisoxazole – an overview | ScienceDirect Topics