The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: cis-Cyclohexane-1,2-dicarboxylic acid(SMILESS: O=C([C@H]1[C@@H](C(O)=O)CCCC1)O,cas:610-09-3) is researched.Related Products of 39901-94-5. The article 《Reduction mechanism of cyclohexene-1,2-dicarboxylic acid》 in relation to this compound, is published in Denki Kagaku oyobi Kogyo Butsuri Kagaku. Let’s take a look at the latest research on this compound (cas:610-09-3).
Reduction mechanism of cyclohexene-1,2-dicarboxylic acid (I) was polarog. examined at pH 0-6. The first of the 3 waves that appeared was due to the adsorption of the product in strongly acid media. The 2nd wave was interpreted as due to a CEC (chem.-electrode-chem.) process involving preprotonation of the acid. The 3rd wave that appeared only in weakly acid media involved a CEC mechanism by which the free acid was reduced. The rate constant of the protonation of the monoanion from I was calculated Controlled-potential electrolysis produced a mixture of trans- and cis-cyclohexanedicarboxylic acid in high yield at pH 0-6. The stereoisomeric ratio of the products was influenced by pH; this was due to the difference of the stability of the reaction intermediates.
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Reference:
Benzisoxazole – Wikipedia,
Benzisoxazole – an overview | ScienceDirect Topics